Characters
From Mario - Wiki on Neoseeker
Baby Daisy » Get at least a star rank in each 50cc Wii Cup
Baby Luigi » Unlock 8 expert staff ghosts in Time Trials
Baby Mario » Default character
Baby Peach » Default character
Birdo » Play through 16 levels in Time Trials
Bowser » Default character
Bowser Jr. » Get at least a star rank in each 100cc Retro Cup
Daisy » Get a trophy in the 150cc Special Cup
Diddy Kong » Get a trophy in all 50cc Cups
Donkey Kong » Default character
Dry Bones » Get a trophy in the 100cc Leaf Cup
Dry Bowser » Get a star rank or better in each of the 150cc Wii stages
Funky Kong » Unlock 4 expert staff ghosts in Time Trials
King Boo » Get a trophy in the 50cc Star Cup
Koopa Troopa » Default character
Luigi » Default character
Mario » Default character
Mii » Outfit A: Get a trophy in the 100cc Special Cup | Outfit B: Unlock all 32 expert staff ghosts
Peach » Default character
Rosalina » Have Super Mario Galaxy data saved onto your Wii and do 50 races / Without SMG data - Attain at least 1 Star Rank for each Mirror Grand Prix Wii Cup
Toad » Default character
Toadette » Play through all 32 levels in Time Trials
Waluigi » Default character
Wario » Default character
Yoshi » Default character
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Carlyon 
on 21:45; 27 June 2008 
last 5 contributors:
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